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Determination of the acid number of biofuels by Titration

Non-aqueous potentiometric acid-base titration

The acid number is a sum parameter for all acidic components; at the same time it is a measure for the long-term stability and corrosiveness of the biofuel. The smaller the value, the higher the quality. Standard EN 14 104 stipulates a non-aqueous potentiometric acid-base titration for determining the acid number. This involves dissolving the sample in a bioethanol/diethyl ether mixture and titrating it with potassium hydroxide dissolved in 2-propanol (1 mol/L). As organic solvents are used, the manual working steps should be reduced to a minimum.


Non-aqueous Titrations by Metrohm

With its space-saving Dosino technology the titrator Titrando allows fully automatic and safe solvent addition. The Solvotrode, an excellently shielded combined pH glass electrode, has been specially developed for non-aqueous titrations. The separable ground-joint diaphragm guarantees stable potentials and is easy to clean.

Product information

809 Titrando 2.809.0010
840 Touch Control 2.840.0100
801 Magnetic Stirrer 2.801.0040
800 Dosino
(2 pcs. for adding titrant and solvent)
2.800.0010
Dosing Unit 20 mL (titrant) 6.3032.220
Dosing Unit 50 mL (solvent) 6.3032.250
Solvotrode (pH measurement) 6.0229.100
Electrolyte
TEABr = 0.4 mol/L in ethylene glycol
6.2320.000
 
   
acid number determination with 809 Titrando
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