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Chloride Content Determination in Bioethanol by Argentometric Titration

The chloride content in bioethanol fuels is the subject of ASTM D 512. Quantitation can be carried out by mercurimetric or argentometric titration or by direct determination with a Cl-selective electrode. Argentometric titration (with silver nitrate) is the method of choice because of its environmental advantages and very high precision. A defined volume of the sample is pipetted into the titration cell, treated with 5 mL nitric acid (2 mol/L) and then titrated against silver nitrate solution (0.01 mol/L).


Titrators by Metrohm

The wide range of potentiometric applications for biofuels requires a highly flexible titrator. No other titration system offers more flexibility and working comfort than the Titrando.

  • With Touch Control, the PC Control software or tiamo – titration and more – operation is child’s play.
  • The space-saving Dosino technology with numerous liquid-handling functions simplifies sample preparation and allows automatic preparation and emptying of burets without operator intervention – it is no longer necessary to handle organic solvents.
  • Intelligent Dosing Units and electrodes eliminate confusion. Extensive GLP functions guarantee safe and error-free work.
  • The Titrando is unbelievably flexible – it covers the whole range from a simple stand-alone titrator up to a fully automatic titration system with sample changer, direct balance connection and barcode reader.

Product information

809 Titrando 2.809.0010
840 Touch Control 2.840.0100
801 Magnetic Stirrer 2.801.0040
800 Dosino
(2 pcs. for adding titrant and nitric acid)
2.800.0010
Dosing Unit 20 mL (titrant) 6.3032.220
Dosing Unit 10 mL (nitric acid) 6.3032.210
Ag Titrode (chloride) 6.0430.100
 
   
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